期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 30, 页码 25291-25297出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b05775
关键词
hydrogen evolution reaction; electrocatalysts; IT-phase MoS2; heterogeneous nanostructure; hydrothermal synthesis; water splitting
资金
- National Natural Science Foundation of China [21673097]
As an electrocatalyst, conventional 2H-phase MoS2 suffers from limited active sites and inherently low electroconductivity. Phase transitions from 2H to IT have been proposed as an effective strategy for optimization of the catalytic activity. However, complicated chemical exfoliation is generally involved. Here, MoS2 heterogeneous-phase nanosheets with a IT phase (1T/2H-MoS2) generated in situ were prepared through a facile hydrothermal method. The locally introduced 1T-phase MoS2 can not only contribute more active sites but also markedly promote the electronic conductivity. Because of this unique structure, the as-synthesized 1T/2H-MoS2 nanosheets exhibit remarkable performance for the hydrogen evolution reaction with a small overpotential of 220 mV at 10 mA/cm(2), a small Tafel slope of 61 mV/decade, and robust stability. This work facilitates the development of a two-dimensional heterogeneous nanostructure with enhanced applications.
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