期刊
CHEMSUSCHEM
卷 10, 期 14, 页码 2891-2896出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201700768
关键词
catalyst stability; feed impurities; levulinic acid; ruthenium; gamma-valerolactone
The presence of biogenic or process-derived impurities poses a major problem on the efficient catalytic hydrogenation of biomass-derived levulinic acid to g-valerolactone; hence, studies on their influence on catalyst stability are now required. Herein, the influence of sulfuric acid as feed impurity on the performance of Ru-based heterogeneous catalysts, including Ru/ZrO2 and mono-and bimetallic Ru-on-carbon catalysts in dioxane as solvent, was investigated. The carbon-supported Ru catalysts proved to be very sensitive to minor amounts of sulfuric acid. In stark contrast, Ru/ZrO2 showed a remarkable stability in the presence of the same impurity, which is attributed to the sulfate-ion adsorption capacity of the support. Preferential sulfate adsorption onto the surface of ZrO2 effectively protects the Ru active phase from deactivation by sulfur poisoning. A simple catalyst regeneration strategy was effective in removing adsorbed impurities, allowing efficient catalyst recycling.
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