期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 10, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201702052
关键词
band alignment; [In-2(phen)(3)Cl-6]center dot CH3CN center dot 2H(2)O; light scattering; metal-organic frameworks; perovskite solar cells
类别
资金
- National Natural Science Foundation of China [21571042, 21371040, 51603055]
- National Key Basic Research Program of China (973 program) [2013CB632900]
- China Postdoctoral Science Foundation [2016M601424]
- Postdoctoral Foundation of Heilongjiang Province [LBH-Z16059]
- Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education
Perovskite solar cells (PSCs) have gained a promising position during the past few years. However, as far as it goes, there is rare combination of the merits of metal-organic framework with PSCs. In this work, a 3D metal-organic framework, namely, [In-2(phen)(3)Cl-6]center dot CH3CN center dot 2H(2)O (In2) is first introduced into hole transport material of PSCs through band alignment engineering. By this facile strategy, the pinholes in the hole transport layer are effectively reduced, and the migration of Au into the entire PSC structure can be alleviated simultaneously. Meanwhile, In2 also plays a role in enhancing the light absorption of perovskite, which is due to: (1) the large particles of In2 acting as light scattering centers; (2) the emission wavelength of In2 is almost the same as the excitation wavelength of perovskite. Consequently, short-current density (J(sc)), open circuit voltage (V-oc), and fill factor (FF) gain a significant increase from 19.53 to 21.03 mA cm(-2), 0.98 to 1.01 V, and 0.67 to 0.74, respectively. Thereby, the power conversion efficiency is remarkably enhanced from 12.8% to 15.8%. In the end, the stability of PSCs should also be improved.
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