期刊
DYES AND PIGMENTS
卷 145, 期 -, 页码 493-504出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2017.06.037
关键词
ESIPT; Tautomer; Salicylideneaniline derivatives; Stokes shift; X-ray diffraction; DFT calculations
资金
- Ministry of Science and Technology in Taiwan [MOST 106-2113-M-035-001]
Three conformationally locked salicylideneaniline derivatives, 1a-1c, were synthesized and characterized by single-crystal X-ray diffraction. Compound la possesses a triply locked configuration, i.e., the intramolecular five-membered-ring C-H center dot center dot center dot N and six-membered-ring O-H center dot center dot center dot N hydrogen bonds and five-membered-ring C(1-6-7-8-9) cydization, from which the excited-state intramolecular proton transfer takes place, resulting in a record high tautomer emission quantum yield of 0.28 in the solid state. Compared with salicylideneaniline, a substantial increase in the emission quantum yield is also observed for 1b and 1c. Furthermore, compound 1a shows pH-dependent optical properties and a highly reversible response to pH, which makes it good candidate for potential applications in pH sensing. Time-dependent density functional theory calculations are reported on these salicylideneaniline derivatives in order to rationalize their electronic structure and optical properties. (C) 2017 Elsevier Ltd. All rights reserved.
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