期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 42, 页码 10013-10016出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702028
关键词
alkynes; copper; fluorine; selenium; trifluoromethylselenolation
资金
- la Region Rhone Alpes
- CNRS
- French Fluorine Network
The successful perfluoroalkylselenolation of alkynyl copper(I) compounds is described herein. The reaction occurs under oxidant free conditions at room temperature. This convenient one-pot procedure is based on the in situ generation of trifluoromethylselenyl chlorides. The developed system shows high functional group tolerance and also promotes the employment of fluoroalkyl derivatives.
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