期刊
ACS CATALYSIS
卷 7, 期 10, 页码 6999-7002出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02658
关键词
carbocations; C-F bond activation; C-H bond activation; cross-coupling; main-group catalysis; silylium ions
资金
- Technische Universitat Berlin
- TU Berlin
Silylium ions facilitate the catalytic direct cross coupling of aryl fluorides with simple arenes and alkanes. This C-H arylation approach is initiated by silylium ion-mediated fluoride abstraction, which is followed by Friedel Crafts or C-H insertion reactions of the resulting phenyl cation equivalents. An o-silyl group in the fluoroarene substrate is the key for selective intermolecular transformations, stabilizing the aryl cation intermediate and serving as an internal silylium ion precursor.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据