期刊
ACS CATALYSIS
卷 7, 期 6, 页码 4115-4121出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b00843
关键词
olefin metathesis; latent catalysts; polymerization; imines; ruthenium; catalysis
资金
- National Science Centre (Poland) [DEC-2012/04A/STS/00594]
- City of Wroclaw [BWU-8/2014/M3]
Analogues of the well-known Hoveyda-Grubbs catalyst bearing both a chelating ester function and a chelating nitrogen atom were obtained. These complexes behave differently depending on the character of the chelating amine. Complexes containing a secondary amine underwent unexpected spontaneous oxidation of the amine group, leading to the Schiff base analogues. In contrast, complexes containing a tertiary amine were prone to intramolecular cyclization in the presence of a base (Et3N). Probing the activity of such (pre)catalysts in ring-closing metathesis reactions (RCMs) revealed their dormant character and excellent thermo-switchability. In particular, complexes bearing an iminium nitrogen fragment were found to be very useful in a delayed ring-opening metathesis polymerization (ROMP) and were therefore commercialized.
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