期刊
ACS CATALYSIS
卷 7, 期 9, 页码 5810-5813出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02105
关键词
polycyclic aromatic hydrocarbon; radicals; cascade cyclization; organic electrochemistry; oxidation
资金
- NSFC [21672178, 21402164, 21603227]
- MOST [2016YFA0204100]
- Thousand Youth Talents Plan
An electrochemical cyclization reaction of easily available urea-tethered diynes has been developed for the synthesis of nitrogen doped polycyclic aromatic hydrocarbons (PAHs). The employment of ferrocene as a mild and selective redox catalyst allows access to a variety of electron-rich PAHs including helicene-like structures without overoxidation. The electrosynthetic method involves an unprecedented amidyl radical cascade cyclization process to form three rings in a single operation.
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