期刊
ACS CATALYSIS
卷 7, 期 10, 页码 6938-6941出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02905
关键词
C-H activation; arylation; transient directing group; beta-amino acid; ketone; palladium
资金
- Scripps Research Institute
- NIH (NIGMS) [2R01GM084019]
- Korea Foundation for Advanced Studies
Palladium-catalyzed methylene beta-C(sp3) H arylation of aliphatic ketones using a transient directing group is developed. The use of alpha-benzyl beta-alanine directing group that forms a six-membered chelation with palladium is crucial for promoting the methylene C(sp3) H bond activation.
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