期刊
ACS CATALYSIS
卷 7, 期 10, 页码 7038-7042出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02341
关键词
core-shell nanomaterials; metal phosphide; oxygen evolution reaction; electrocatalysis
资金
- Ministry of Education, Youth and Sports of the Czech Republic [LO130S]
- NSFC [21401066]
- Jilin Province Science and Technology Development Plan [20150520003JH]
- Education Department of Jilin Province [410]
- ETH [SEED-14 17-1]
- [LM2015073]
We present a facile synthetic method that yields Ag@CoxP core-shell-type heterogeneous nanostructures with excellent oxygen evolution reaction (OER) activity. This nanocatalyst can deliver a current density of 10 mA/cm(2) at a small overpotential of 310 mV and exhibits high catalytic stability. Additionally, the catalytic activity of Ag@CoxP is 8 times higher than that of the Co2P nanoparticles, owing primarily to the strong electronic interaction between the Ag core and the CoxP shell.
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