4.8 Article

Ag@CoXP Core-Shell Heterogeneous Nanoparticles as Efficient Oxygen Evolution Reaction Catalysts

期刊

ACS CATALYSIS
卷 7, 期 10, 页码 7038-7042

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b02341

关键词

core-shell nanomaterials; metal phosphide; oxygen evolution reaction; electrocatalysis

资金

  1. Ministry of Education, Youth and Sports of the Czech Republic [LO130S]
  2. NSFC [21401066]
  3. Jilin Province Science and Technology Development Plan [20150520003JH]
  4. Education Department of Jilin Province [410]
  5. ETH [SEED-14 17-1]
  6. [LM2015073]

向作者/读者索取更多资源

We present a facile synthetic method that yields Ag@CoxP core-shell-type heterogeneous nanostructures with excellent oxygen evolution reaction (OER) activity. This nanocatalyst can deliver a current density of 10 mA/cm(2) at a small overpotential of 310 mV and exhibits high catalytic stability. Additionally, the catalytic activity of Ag@CoxP is 8 times higher than that of the Co2P nanoparticles, owing primarily to the strong electronic interaction between the Ag core and the CoxP shell.

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