期刊
ACS CATALYSIS
卷 8, 期 1, 页码 86-89出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b03079
关键词
nickel catalysis; bidentate ligand; Suzuki reaction; alcohol electrophile; allylic arylation
资金
- American Chemical Society Petroleum Research Fund [56371-DNI1]
- National Science Foundation [CHE-1665015]
Cross couplings between simple allylic alcohols and aryl and vinyl boronic acids are efficiently catalyzed by nickel(0) catalysts and bidentate N-heterocyclic carbene/phosphine ligands. The bidentate nature of the ligand is shown to extend catalyst lifetime and enable high yields of the corresponding cross-coupling products. X-ray crystallography confirms the bidentate nature of the ligand scaffold. Multistep cross coupling-alkene/alkyne insertions reactions are also conducted and the bidentate nature of the substrate makes the pendant phosphine of the ligand unnecessary.
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