期刊
ACS CATALYSIS
卷 7, 期 9, 页码 6220-6224出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01847
关键词
copper; C-C coupling; alkynes; arenes; synthetic methods
资金
- University of Illinois
- NSF CAREER [1555337]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1555337] Funding Source: National Science Foundation
The copper-catalyzed hydroarylation of internal, unsymmeric alkynes is presented. Trisubstituted alkenes are obtained as single diastereomers in good to excellent yields and excellent regioselectivities. The scope of the reaction is presented with respect to alkyne and aryl iodide coupling partners. Initial mechanistic experiments indicate a hydrocupration event followed by a two-electron oxidative addition/reductive elimination pathway.
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