期刊
ACS CATALYSIS
卷 7, 期 8, 页码 5194-5201出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01735
关键词
photocatalysis; visible light; alloy nanoparticle; hot electron; dehalogenation
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT) [26289296]
- Grants-in-Aid for Scientific Research [26289296] Funding Source: KAKEN
Dehalogenation of aromatic halides is one important reaction for detoxification and organic synthesis. Photocatalytic dehalogenation with alcohol, a safe hydrogen source, is one promising method; however, systems reported earlier need UV irradiation. We found that Pt-Pd bimetallic alloy nanoparticles (ca. 4 nm) supported on Ta2O5 (PtPd/Ta2O5), on absorption of visible light (lambda > 450 nm), efficiently promote dehalogenation with 2-PrOH as a hydrogen source. Catalytic dehydrogenation of 2-PrOH on the alloy in the dark produces hydrogen atoms (H) on the particles. Photoexcitation of d electrons on the alloy particles by absorbing visible light produces hot electrons (e(ho)t(-)). They efficiently reduce the adsorbed, H atoms and produce hydride species (H-) active for dehalogenation. The catalytic activity depends on the Pt/Pd mole ratio; alloy particles consisting of 70 mol % of Pt and 30 mol % of Pd exhibit the highest activity for dehalogenation.
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