期刊
ACS CATALYSIS
卷 7, 期 6, 页码 3832-3836出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b00731
关键词
palladium; isocyanide; asymmetric catalysis; C-H bond activation; 3,4-dihydroisoquinoline
资金
- National Natural Science Foundation of China [21272233, 21472190, 21573095]
An efficient palladium-catalyzed enantioselective isocyanide insertion/desymmetrizing C(sp(2))-H bond activation reaction allowed by a SPINOL-derived phosphoramidite ligand was developed. 3,4-Dihydroisoquinolines containing C3 quaternary stereogenic centers were obtained in high yields with good enantioselectivity under mild conditions.
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