期刊
ACS CATALYSIS
卷 7, 期 3, 页码 1606-1609出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b03529
关键词
silver-catalyzed; radical hydroxyfluorination; anti-Markovnikov; fluorohydrins; styrenes
资金
- State Key Laboratory of Elemento-organic Chemistry
- National Program on Key Research Project [2016YFA0602900]
- Natural Science Foundation of China [21402098, 21421062, 21522205]
A silver-catalyzed radical hydroxyfluorination of styrenes with Selectfluor and H2O has been explored with exclusive anti-Markovnikov-type regioselectivity, thus affording vicinal fluorohydrins with regioselectivities opposite that of noncatalyzed processes. This reaction is operationally simple, scalable under mild conditions. The mechanism studies and DFT calculations revealed that the reaction go through a radical mechanism.
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