期刊
ACS CATALYSIS
卷 7, 期 7, 页码 4473-4478出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01159
关键词
C4 aldose; retro-aldol/aldol condensation; stabilizing effect; biomass; heterogeneous catalysis
资金
- 973 Program [2013CB934101]
- NSFC [21673045, U1463206, 21473037, 21433002]
Highly efficient transformations of biomass derived sugars into various valuable chemicals are of topical interest. Tetrose with a four-carbon bone is the root of most of biomass-derived C4 products, but its extreme instability obstructs the blossoming of C4 products presently. Herein, we describe a borate-stabilized catalytic strategy to accumulate erythrose from C6 aldose in a highly selective manner via retro-aldol and aldol processes in alcohol solvent. In our proposed mechanism, borate can stabilize erythrose and avoid its further retro-aldol splitting or isomerization, and induce the production of erythrose again via the aldol condensation of the above-generated glycolaldehyde.
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