期刊
ACS CATALYSIS
卷 7, 期 12, 页码 8533-8543出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b03081
关键词
allylic oxidation; allylic esterification; allylic amination; allylic alkylation; internal alkenes; enantioselective catalysis; enantioselective heteroene
资金
- Welch Foundation [I-1748]
- National Institutes of Health [R01GM102604]
- National Science Foundation [1150875]
- Sloan Research Fellowship
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1150875] Funding Source: National Science Foundation
The asymmetric allylic functionalization of unactivated internal alkenes is an emerging strategy for the conversion of simple unsaturated starting materials into a diverse range of enantioenriched products. This Perspective summarizes the development of reactions wherein a chiral catalyst facilitates the intermolecular stereoselective reaction between an achiral unactivated internal alkene and a reagent.
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