期刊
ACS CATALYSIS
卷 8, 期 1, 页码 310-313出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b03388
关键词
alkyl electrophiles; beta-hydride elimination; 1,1-diarylalkanes; migratory cross-coupling; high-valent nickel
资金
- Wuhan University
- National Science Foundation of China [21702151]
1,1-Diarylalkanes are important structural frameworks which are widespread in biologically active molecules. Herein, we report a reductive relay cross-coupling of alkyl bromides with aryl bromides by nickel catalysis with a simple nitrogen-containing ligand. This method selectively affords 1,1-diarylalkane derivatives with good to excellent yields and regioselectivity.
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