期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 62, 页码 8731-8734出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04131d
关键词
-
资金
- Nanjing Tech University [39837110]
- SICAM Fellowship by Jiangsu National Synergetic Innovation Center for Advanced Materials
The manganese-catalyzed a-fluoroalkenylation of arenes via C-H activation and C-F cleavage has been described. This protocol provides a very useful method for the synthesis of monofluoroalkenes with predominant unconventional E-isomer selectivity which complements the existing strategies for the access to these molecular architectures. In addition, the selectivity of beta-defluorination in the catalytic cycle not only determines the configurations of the products but also obviates the use of external oxidants, providing a good example in the exploitation of manganese-catalyzed redox-neutral C-H transformations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据