期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 63, 页码 8882-8885出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03556j
关键词
-
资金
- National Natural Science Foundation of China [21673016]
- 973 Project [2014CB932101]
A heterogeneous enantioselective oxa-Michael-Michael reaction for the synthesis of chromans has been developed on a heterogeneous acid-base synergic catalyst with inherent silica as acidic sites and immobilized chiral amines as basic sites. Final products were afforded in selectivity of up to 98% and ee of 97% from 2-nitrovinyl phenol and 3-methyl-2-butenal. The heterogeneous synergistic catalytic mechanism has also been studied.
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