期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 211, 期 -, 页码 157-166出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2017.04.037
关键词
Ion-exchange method; Raspberry-like; TiO2/Fe2TiO5/Fe2O3; Photo-Fenton reaction
资金
- National Nature Science Foundation of China [21577036, 21377038, 21237003, 21677048]
- National Basic Research Program of China (973 Program) [2013CB632403]
- State Key Research Development Program of China [2016YFA0204200]
- Chenguang Program - Shanghai Education Development Foundation
- Shanghai Municipal Education Commission [14CG30]
- Science and Technology Commission of Shanghai Municipality [16JC1401400]
- Fundamental Research Funds for the Central Universities [22A201514021, 222201717003]
The construction of catalysts with high efficiency and stability for heterogeneous Photo-Fenton reaction Heterogeneous (PFR) has been a major challenge for the degradation of organic pollutants. Here, we successfully develop an advanced TiO2/Fe2TiO5/Fe2O3 triple-heterojunction structure by using the mesoporous TiO2 spheres as the substrate via a simple ion-exchange method. The XRD and HRTEM results demonstrate the generation of Fe2TiO5 on the interface between TiO2 and Fe2O3, which can be used as a bridge to transfer the photo-excited electrons from TiO2 to Fe2O3. The as-prepared triple-heterojunction has abundant interphase boundaries which greatly improve the migration of photo-excited charges among different components. As a result, the prepared triple-heterojunction has a significantly enhanced PFR activity for the visible-light-driven degradation of methyl orange (MO) and colorless organic pollutant of phenol, compared with the single catalysts of Fe2O3 and TiO2, and the binary-heterojunction of TiO2/Fe2O3. Compared to the traditional Fe2O3 based PFR, the degradation rates of MO and phenol over triple-heterojunction can be increased from 4% to 87% within 10 min irradiation and from 38% to 100% within 60 min irradiation, respectively. And the total organic carbon (TOC) degradation rate of phenol can be up to 85%. Moreover, this advanced triple-heterojunction has a wide pH value range of application in PFR. Either at a pH of 4.0 or 7.0, it shows a much higher and more stable PFR activity for the degradation of MO than the catalysts of Fe2O3 and TiO2/Fe2O3. And the reaction rate of TiO2/Fe2TiO5/Fe2O3 almost keeps changeless even after 10th cycles, suggesting its vast application foreground in the environmental pollutant treatment. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据