期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 12, 期 13, 页码 1517-1522出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201700209
关键词
carbon nitride; eutectic salt melts; organic zeolites; poly(heptazine imide); porous solid polyelectrolytes
Highly crystalline potassium (heptazine imides) were prepared by the thermal condensation of substituted 1,2,4-triazoles in eutectic salt melts. These semiconducting salts are already known to be highly active photocatalysts, for example, for the visible-light-driven generation of hydrogen from water. Herein, we show that within the solid-state structure, potassium ions can be exchanged to other metal ions while the crystal habitus is essentially preserved.
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