期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 35, 页码 10521-10524出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201704068
关键词
amines; aryl migration; photocatalysis; redox-neutral reactions; remote functionalization
资金
- European Research Council (ERC) [307948]
- Swiss National Science Foundation [SNF 200020_146853]
- Swiss National Science Foundation (SNF) [200020_146853] Funding Source: Swiss National Science Foundation (SNF)
Cleavage of unstrained C-C bonds under mild, redox-neutral conditions represents a challenging endeavor which is accomplished here in the context of a flexible, visiblelight-mediated, gamma-functionalization of amines. In situ generated C-centered radicals are harvested in the presence of Michael acceptors, thiols and alkyl halides to efficiently form new C(sp(3))-C(sp(3)), C(sp(3))-H and C(sp(3))-Br bonds, respectively.
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