期刊
ACS NANO
卷 11, 期 7, 页码 7485-7493出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.7b04020
关键词
Janus particles; ToF-SIMS; asymmetric functionalization; grafting-from; graphene oxide
类别
资金
- CWRU College of Arts and Sciences
- NSF CAREER [1551943]
- NASA [NNX13AR93H]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1551943] Funding Source: National Science Foundation
- NASA [NNX13AR93H, 463850] Funding Source: Federal RePORTER
Janus particles have recently garnered significant attention for their distinct properties compared to particles that are homogeneously functionalized. Moreover, high aspect ratio Janus particles that are rod-like or planar (i.e., nanosheets) are especially intriguing considering their interfacial properties as well as their ability to assemble into higher order and hybrid structures. To date, major challenges facing the exploration and utilization of 2D Janus particles are scalability of synthesis, characterization of tailored chemical functionalization, and ability to introduce a diverse set of functionalities. Herein, a facile method to access Janus 2D graphene oxide (GO) nanosheets by combining a Pickering-type emulsion and grafting-from polymerization via ATRP is reported. Janus GO nanosheets bearing PMMA on one face as well as the symmetrically functionalized analogue are prepared, and the chemical, thermal, structural, surface, and interfacial properties of these materials are characterized. Time-of-flight secondary ion mass spectrometry coupled with Langmuir Blodgett films is shown to be an ideal route to conclusively establish asymmetric functionalization of 2D materials. This work not only provides a facile route for the preparation of Janus nanosheets but also demonstrates the direct visualization of polymer grown from the surface of GO.
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