Highly active iridium catalyst for hydrogen production from formic acid

Formic acid (FA) dehydrogenation has attracted a lot of attentions since it is a convenient method for H-2 production. In this work, we designed a self-supporting fuel cell system, in which H-2 from FA is supplied into the fuel cell, and the exhaust heat from the fuel cell supported the FA dehydrogenation. In order to realize the system, we synthesized a highly active and selective homogeneous catalyst IrCp*CL(2)bpym for FA dehydrogenation. The turnover frequency (TOF) of the catalyst for FA dehydrogenation is as high as 7150 h(-1) at 50 degrees C, and is up to 144,000h(-1) at 90 degrees C. The catalyst also shows excellent catalytic stability for FA dehydrogenation after several cycles of test. The conversion ratio of FA can achieve 93.2%, and no carbon monoxide is detected in the evolved gas. Therefore, the evolved gas could be applied in the proton exchange membrane fuel cell (PEMFC) directly. This is a potential technology for hydrogen storage and generation. The power density of the PEMFC driven by the evolved gas could approximate to that using pure hydrogen. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.