期刊
CHEMICAL RECORD
卷 17, 期 7, 页码 667-680出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201600139
关键词
Flow chemistry; Green chemistry; Real-time monitoring; Process intensification; Photochemistry
资金
- Novartis-MIT Center for Continuous Manufacturing
- Bill and Melinda Gates Foundation
- Defense Advanced Research Project Agency (DARPA)
- NSERC Canada
Technological advances have an important role in the design of greener synthetic processes. In this Personal Account, we describe a wide range of thermal, photochemical, catalytic, and biphasic chemical transformations examined by our group. Each of these demonstrate how the merits of a continuous flow synthesis platform can align with some of the goals put forth by the Twelve Principles of Green Chemistry. In particular, we illustrate the potential for improved reaction efficiency in terms of atom economy, product yield and reaction rates, the ability to design synthetic process with chemical and solvent waste reduction in mind as well as highlight the benefits of the real-time monitoring capabilities in flow for highly controlled synthetic output.
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