期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 67, 页码 9352-9355出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04035k
关键词
-
资金
- NRF of Korea through CRI [NRF-2012R1A3A2048842]
- GRL [NRF-2010-00353]
- Basic Science Research Program [2017R1D1A1B03029982, 2017R1D1A1B03032615]
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) [16H02268]
- SENTAN from Japan Science and Technology Agency, Japan
- JSPS
- Grants-in-Aid for Scientific Research [16H02268] Funding Source: KAKEN
Direct oxygen atom transfer from a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)Mn-IV(O)](2+), to triphenylphosphine (Ph3P) derivatives occurs with a significant steric effect resulting from the ortho-substituents on the phenyl group of the Ph3P derivatives, whereas the phosphine oxygenation by a Mn(IV)-oxo complex in the presence of HOTf occurs via an electron transfer mechanism without the substrate-steric effect.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据