4.6 Article

Underscreening, overscreening and double-layer capacitance

期刊

ELECTROCHEMISTRY COMMUNICATIONS
卷 82, 期 -, 页码 129-133

出版社

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2017.07.008

关键词

Concentrated electrolytes; Room temperature ionic liquids; Debye length; Mean-field; Underscreening; Overscreening

资金

  1. Alexander von Humboldt Foundation
  2. Thomas Young Centre (UK)
  3. Engineering and Physical Sciences Research Council [EP/H004319/1] Funding Source: researchfish
  4. EPSRC [EP/H004319/1] Funding Source: UKRI

向作者/读者索取更多资源

There have recently been reports of extraordinarily long screening lengths in concentrated electrolytes and which vary non-monotonically with ion concentration. There were several attempts to explain these puzzling observations. In this communication we further explore possibilities to rationalise those results. Our analysis does not yet close the problem, but it highlights conflicting consequences of the models designed to reproduce those observations.

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