期刊
CATALYSIS COMMUNICATIONS
卷 100, 期 -, 页码 62-65出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2017.06.014
关键词
UHP/silica sulfuric acid; Heterogeneous catalyst; Oxidation; Sulfides; Green chemistry
资金
- Research Councils of the Iran University of Science and Technology
- Lorestan University
An efficient and green protocol was used for the selective oxidation of sulfides to sulfoxides by using silica sulfuric acid (SSA) as a recoverable heterogeneous solid acid catalyst in the presence of urea-hydrogen peroxide (UHP) under toxic transition metal-, solvent- and halogen-free conditions at room temperature. The present method offers several noteworthy advantages, such as high product yields, easy work-up, non-toxicity, easy preparation and reusability of the catalyst for at least six runs, which make this procedure the most convenient and attractive with low cost of catalyst and oxidant.
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