期刊
CHEMICAL SCIENCE
卷 8, 期 4, 页码 2610-2615出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc05093j
关键词
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资金
- Natural Science Foundation of China
- Shandong province [21572118, JQ201505]
- fundamental research and subject construction funds [2014JC008, 104.205.2.5]
- Shandong University
Regioselective difunctionalization of alkenes has attracted significant attention from synthetic chemists and has the advantage of introducing diverse functional groups into vicinal carbons of common alkene moieties in a single operation. Herein, we report an unprecedented intermolecular atom transfer thiosulfonylation reaction of alkenes by combining gold catalysis and visible-light photoredox catalysis. A trifluoromethylthio group (SCF3) and other functionalized thio groups together with a sulfonyl group were regioselectively introduced into alkenes in the most atom economical manner. A detailed mechanism study indicated that a synergistic combination of gold catalysis and photoredox catalysis is crucial for this reaction.
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