期刊
CHEMICAL SCIENCE
卷 8, 期 10, 页码 7009-7013出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc03010j
关键词
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资金
- EPFL
- Swiss National Science Foundation [200020_152850/1]
- Swiss National Science Foundation (SNF) [200020_152850] Funding Source: Swiss National Science Foundation (SNF)
Photoredox catalysis has been developed to achieve oxidative C-H chlorination of aromatic compounds using NaCl as the chlorine source and Na2S2O8 as the oxidant. The reactions occur at room temperature and exhibit exclusive selectivity for C(sp(2))-H bonds over C(sp(3))-H bonds. The method has been used for the chlorination of a diverse set of substrates, including the expedited synthesis of key intermediates to bioactive compounds and a drug.
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