期刊
CHEMICAL SCIENCE
卷 8, 期 3, 页码 2175-2178出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc04480h
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资金
- National Natural Science Foundation of China [21562026, 21262018]
- JiangXi Provincial Natural Science Foundation of China [20161BAB203085]
Selective carbon-carbon and carbon-heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O-2 assisted the bond cleavage and the leaving groups from the starting materials were trapped by O-2 and underwent a hydroxylation process.
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