期刊
CHEMICAL SCIENCE
卷 8, 期 2, 页码 864-877出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc04157d
关键词
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资金
- Royal Society for a University Research Fellowship
- EPSRC
- Pfizer
- Engineering and Physical Sciences Research Council [1502977, EP/N005422/1] Funding Source: researchfish
- EPSRC [EP/N005422/1] Funding Source: UKRI
Asymmetric catalysis has been revolutionised by the realisation that attractive non-covalent interactions such as hydrogen bonds and ion pairs can act as powerful controllers of enantioselectivity when incorporated into appropriate small molecule chiral scaffolds. Given these tremendous advances it is surprising that there are still a relatively limited number of examples of non-covalent interactions being harnessed for control of regioselectivity or site-selectivity in catalysis, two other fundamental selectivity aspects facing the synthetic chemist. This perspective examines the progress that has been made in this area thus far using non-covalent interactions in conjunction with transition metal catalysis as well as in the context of purely organic catalysts. We hope this will highlight the great potential in this approach for designing selective catalytic reactions.
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