期刊
CHEMICAL SCIENCE
卷 8, 期 4, 页码 2574-2580出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc05135a
关键词
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资金
- Program for Element Strategy Initiative for Catalysts & Batteries (ESICB)
- Precursory Research for Embryonic Science and Technology (PRESTO)
- Japan Science and Technology Agency (JST)
- Japan Society for the Promotion of Science (JSPS) [26289307, 15K18269]
- MEXT
- Kindai University
- JSPS
- Grants-in-Aid for Scientific Research [15K18269, 26289307] Funding Source: KAKEN
We found that plasmonic Au particles on titanium(IV) oxide (TiO2) act as a visible-light-driven photocatalyst for overall water splitting free from any additives. This is the first report showing that surface plasmon resonance (SPR) in a suspension system effectively induces overall water splitting. Modification with various types of metal nanoparticles as co-catalysts enhanced the evolution of H-2 and O-2. Among these, Ni-modified Au/TiO2 exhibited 5-times higher rates of H-2 and O-2 evolution than those of Ni-free Au/TiO2. We succeeded in designing a novel solar energy conversion system including three elemental technologies, charge separation with light harvest and an active site for O-2 evolution (plasmonic Au particles), charge transfer from Au to the active site for H-2 production (TiO2), and an active site for H-2 production (Ni cocatalyst), by taking advantage of a technique for fabricating size-controlled Au and Ni nanoparticles. Water splitting occurred in aqueous suspensions of Ni-modified Au/TiO2 even under irradiation of light through an R-62 filter.
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