期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 38, 页码 11485-11489出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705720
关键词
alkenes; boron; cyclization; reaction mechanisms; total synthesis
资金
- U.S. National Institutes of Health, Institute of General Medical Sciences [GM 59417]
We describe an unusual net [2+2] cycloaddition reaction between boron alkylidenes and unactivated alkenes. This reaction provides a new method for the construction of carbocyclic ring systems bearing versatile organoboronic esters. Aside from surveying the scope of this reaction, we provide details about the mechanistic underpinnings of this process, and examine its application to the synthesis of the natural product aphanamal.
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