期刊
CHINESE JOURNAL OF CATALYSIS
卷 38, 期 8, 页码 1390-1398出版社
ELSEVIER
DOI: 10.1016/S1872-2067(17)62881-X
关键词
Rhodium; C-H activation; [4+1] annulation; Propargyl alcohol; Isoindolinones
资金
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- National Natural Science Foundation of China [21525208, 21472186]
A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(III)-catalyzed C-H activation of benzamides and [4 + 1] coupling with propargyl alcohols. This coupling system proceeds with broad substrate scope and mild conditions and provides a new approach to access the useful skeleton of gamma-lactams with a stereogenic center. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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