期刊
CARBOHYDRATE POLYMERS
卷 174, 期 -, 页码 291-298出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2017.06.080
关键词
Cellulose nanocrystal; Crystal structure; Regioselectivity; Size uniformity
资金
- Special Fund for Forest Scientific Research in the Public Welfare [201504603]
- Priority Academic Program Development of Jiangsu Higher Education Institutions, China
This work was to investigate the influence of time on the properties of cellulose nanocrystals (CNCs) during the ammonium persulfate (APS) oxidation of hybrid poplar residues (HPHL). The CNCs at the different times were characterized by different techniques. The results showed that CNCs were thinned and shortened with increased oxidation time, and their yield, crystallinity index and zeta potential increased, however, these properties stayed constant after the APS oxidation for 16 h. At this time, the CNC yield was more than 50%, and the CNCs had a zeta potential of -48.84 mV and a CrI of 86.8%. More than 95% of CNCs had a width of 16.87 +/- 5.92 nm, and 86.4% of them had a length-to-width ratio from 10 to 30. The primary hydroxyl groups were regioselectively oxidized during the APS treatment. Therefore, the CNCs with stable properties could be extracted from HPHL using APS oxidation. (C) 2017 Elsevier Ltd. All rights reserved.
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