期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 39, 页码 11870-11874出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706719
关键词
asymmetric catalysis; boron; cross coupling; nickel
资金
- NIH [GM-118641]
Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.
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