期刊
CRYSTENGCOMM
卷 19, 期 34, 页码 4955-4959出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce01070b
关键词
-
资金
- Fondazione Cariplo (project PHAEDRA) [2014-0746, RFJ4RIST01]
Single crystal X-ray analysis shows that intermolecular C-S center dot center dot center dot F chalcogen bonds are by far the shortest contacts in the crystal structure of 2,2,4,4-tetrafluoro-1,3-dithietane. Analysis of the molecular surface electrostatic potentials indicates that these contacts result from the attraction between the negative potentials of fluorines and the positive regions resulting from the overlapping of sulfur and carbon positive s-holes. In contrast, the lattice structure of 2,2,4,4-tetrachloro-1,3-dithietane is controlled by intermolecular C-Cl. Cl halogen bonds. The lattices of the two systems are thus controlled by two different sigma-hole interactions.
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