期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 39, 页码 11769-11773出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201704940
关键词
conformation analysis; mechanochemistry; scanning probe microscopy; surface chemistry; tin
资金
- National Natural Science Foundation of China [21522301, 21373020, 21403008, 61321001, 21433011, 11304107, 61371015]
- Ministry of Science and Technology [2014CB239302, 2013CB933404, 2017YFA0205003]
- Deutsche Forschungsgemeinschaft [Sonderforschungsbereich 677]
Atomic-scale mechanochemistry is realized from force exerted by a C-60-functionalized scanning tunneling microscope tip. Two conformers of tin phthalocyanine can be prepared on coinage-metal surfaces. A transition between these conformers is induced on Cu(111) and Ag(100). Density-functional calculations reveal details of this reaction. Because of the large energy barrier of the reaction and the strong interaction of SnPc with Cu(111), the process cannot be achieved by electrical means.
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