期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 70, 页码 9701-9704出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05150f
关键词
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资金
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Key Program of Frontier Sciences, CAS [QYZDJ-SSW-SLH033]
- National Natural Science Foundation of China [21373221, 21521061, 51672271, 21671190, 21403236, 21401192, 21403176]
- Natural Science Foundation of Fujian Province [2006L2005]
- Chinese Postdoctoral Science Foundation [2016M600509]
Lone pair-pi interaction-induced charge-transfer was successfully used for switching the conductance of a coordination network, through variation of the degree of charge transfer caused by external photostimulation. The underlying mechanism is attributed to the changes in efficient charge-carriers by photoinduced strong charge transfer, which was investigated by in situ UV-Vis absorption, ESR, and computational studies.
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