期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 73, 页码 10196-10199出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06054h
关键词
-
资金
- Polish budget for science and education
- Polish Ministry of Science and Higher Education [IdP 2012/0002/62]
- European Union from the European Regional Development Fund
A versatile method for the post-synthetic removal of primary amino groups from metal-organic frameworks (MOFs) has been developed. The method allowed the first successful synthesis of the missing parent compound of an important family of MOFs - the unsubstituted (Al)MIL-101. The material was shown to be a useful reference compound for the elucidation of the role of amino groups in the adsorption and deactivation of olefin metathesis catalysts. The chemoselectivity of the deamination is sufficient for the selective removal of NH2 substituents from mixed-linker MOFs bearing both NH2 and RCONH groups.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据