期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 40, 页码 12356-12360出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707505
关键词
fenestrane; nanographene; polycyclic aromatic compounds; saddle-shaped structures; Scholl cyclization
资金
- RGC-CRF [C4030-14G]
- UGC-AoE of HKSAR [AoE/P-03/08]
Two saddle-shaped polycyclic aromatic compounds (8a and 8b) bearing an all-cis-[5.5.5.5]fenestrane core surrounded by an o,p,o,p,o,p,o,p-cyclooctaphenylene belt were synthesized and characterized by NMR spectroscopy and mass spectrometry. The key step of this synthesis involves the formation of four cycloheptatriene rings from the corresponding electron-rich 1,4,9,12-tetraarylfenestrindane derivatives 7a and 7b in Scholl-type cyclizations. The structural details of the D-2d-symmetric saddle compound 8a were determined by X-ray crystallography, and the properties of 8a and 8b were studied by UV/Vis and fluorescence spectroscopy and cyclic voltammetry.
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