期刊
ADVANCED MATERIALS
卷 29, 期 36, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201604878
关键词
nanocrystals; oleic acid and oleylamine; surface functionalization; thiol-ene click; water soluble
类别
资金
- National Natural Science Foundation of China (NSFC) [51332008, 51472231, 51628201]
- National Basic Research Program of China [2014CB643803]
- Projects for Science and Technology Development Plan of Jilin Province [20170101187JC, 20170414003GH]
Oleic acid (OA) and/or oleylamine (OAm) are generally used as the surface ligands for stabilization of inorganic nanocrystals (NCs). The hydrophobic and inert surface of the NCs limits their applications such as in biomedical areas. Hence, surface modifications are essential in many physical and chemical processes. Here, a facile and versatile strategy is reported for the modification of NCs by ultraviolet-induced thiol-ene chemistry, in which thiol-terminated poly(ethylene glycol) (HSPEG) and its derivatives can react directly with double bonds in OA/OAm ligands to form covalent linking within one step. Through this strategy, various hydrophobic NCs with different compositions and morphologies are able to be transferred into water combining with functionalization of active groups. As a proof-of-concept, this strategy is successfully used to construct a sensor for detecting avidin based on upconverting luminescence analysis. Therefore, this strategy provides a new tool for designing and tuning the surface properties of NCs for different applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据