期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 76, 页码 10544-10547出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05444k
关键词
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资金
- National Natural Science Foundation of China [21331004, 21673140, 21671134]
- Innovation Program of Shanghai Science and Technology Committee [16JC1401600]
- Shanghai Eastern Scholar Program
- Shanghai Rising-Star Program [16QA1402100]
- SJTU-MPI partner group
The oxygen evolution reaction (OER) is the rate-limiting process for water splitting, and highly efficient large-area OER photoanodes have been considered as an essential part in photoelectrochemical water splitting reactors. The high hole-electron separation efficiency of photoanodes is highly required for real applications of photoanodes in sufficiently harvesting solar energy. Herein we show that the inactive g-C3N4 nanolayers can be self-assembled with BiVO4 into a highly coupled BV/CN dyad to significantly enhance the charge separation efficiency of BiVO4 photoelectrodes for the OER. The incident photon-to-current conversion efficiency (IPCE) of visible light (400 nm) provided by the scalable BV/CN-5 photoanode was estimated to be 50% at 1.23 V vs. RHE in 0.5 M Na2SO4 solution and significantly increased to 97% at a bias voltage of 1.6 V vs. RHE.
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