期刊
COMPOSITES SCIENCE AND TECHNOLOGY
卷 150, 期 -, 页码 135-140出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compscitech.2017.07.001
关键词
Thermoelectric; Elastic properties; Nano composites; Polyaniline
资金
- National Key Research and Development Program of China [2016YFA0201103]
- Shanghai Government [15JC1400301]
- National Natural Science Foundation of China [51632010]
Combining thermoelectric (TE) properties and elastic features of organic materials will be unique and fascinating, which is difficult for traditional inorganic TE materials. However, organic materials with good elasticity always show poor electrical conductivity as well as low TE performance. Herein, we composite polyaniline (PANI) with three-dimensional tubular graphene (3D graphene) for high-performance elastic TE materials. It was found this method overcame the commonly encountered dispersing problem of graphene and therefore maximized the amount of the interfaces between graphene and PANI, which contributed to a relatively high Seebeck coefficient and low thermal conductivity. As a result, a maximum ZT value of 0.02 was achieved at room temperature in 55 wt% 3D graphene/PANI composite bulks, which was among the top level for PANI based composite TE bulks. Fuithermore, the elastic composite bulks also exhibited mechanical-stable TE properties, with negligible performance change after 100 times 50% compression cycles. It is the first time to fabricate polymer based bulks with such excellent TE properties and elasticity to the best of our knowledge. This work demonstrates a new strategy for preparing highperformance elastic TE materials. (C) 2017 Published by Elsevier Ltd.
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