期刊
CHEMISTRY OF MATERIALS
卷 29, 期 17, 页码 7054-7061出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.7b02245
关键词
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资金
- NSF CAREER [DMR-1553634]
- Research Corporation for Science Advancement
- Alfred P. Sloan Research Fellowship
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1553634] Funding Source: National Science Foundation
Merging the intrinsic properties of fullerene (buckyball) and corannulene (buckybowl) derivatives with the inherent properties of crystalline metal- and covalent-organic frameworks (MOFs and COFs), including their modularity, porosity, versatility, high surface area, and structural tunability, opens a pathway to unlock a novel class of fulleretic materials. Despite the great interest in MOFs and COFs, as well as fullerene derivatives, this perspective is the first overview focusing solely on crystalline fullerene- and corannulene-containing frameworks, highlighting their potential contributions in the fields of optoelectronic devices, electrodes, and photosensitizers. We revealed a dual role of fullerene- and corannulene-containing building blocks showing their versatility to act as either a framework linker or a guest inside the pores. This perspective encompasses a rising new field in which fulleretic crystalline frameworks are not only structural and synthetic masterpieces but also valuable potential materials to the ever-expanding technological landscape.
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