期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 34, 页码 28604-28611出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b08704
关键词
bacterial cellulose; carbonization; highly N-doped; three-dimensional; sodium storage
资金
- National Natural Science Foundation [21573083]
- 1000 Young Talent
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Waterloo
- Waterloo Institute for Nanotechnology
- China Scholarship Council (CSC)
Inspired by the excellent absorption capability of spongelike bacterial cellulose (BC), three-dimensional hierarchical porous carbon fibers doped with an ultrahigh content of N (21.2 atom %) (i.e., nitrogen -doped carbon fibers, NDCFs) 800 were synthesized by an adsorption swelling strategy using BC as the carbonaceous 0) material. When used as anode materials for sodium-ion batteries, the NDCFs deliver a 600 high reversible capacity of 86.2 mAh g(-1). even after 2000 cycles at a high current density of 10.0 A g(-1). It is proposed that the excellent Na+ storage performance is mainly due to the defective surface of the NDCFs created by the high content of N dopant. Density functional theory (DFT) calculations show that the defect sites created by N doping can strongly host Na+ and therefore contribute to the enhanced storage capacity.
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