期刊
GREEN ENERGY & ENVIRONMENT
卷 2, 期 4, 页码 370-376出版社
KEAI PUBLISHING LTD
DOI: 10.1016/j.gee.2017.05.001
关键词
CO2; Polyurea; Two-step polymerization; Catalysis
类别
资金
- National Basic Research Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21672204, 21273222]
- Youth Innovation Promotion Association CAS [2016206]
- Jilin Provincial Science and Technology Program of China [20160203007GX]
Activation and transformation of CO2 is one of the important issues in the field of green and sustainable chemistry. Herein, CO2 as a carbon-oxygen resource was converted to CO2-polyurea with 1,6-hexanediamine through a two-step polymerization. The reaction parameters such as temperature, pressure and reaction time were examined; and several kinds of catalysts were screened in the absence and presence of NMP solvent. The formed oligomer and the final polyurea were characterized by FT-IR, VT-DRIFTS, NMR, XRD, AFM and their thermal properties were examined by TGA and DSC. It was confirmed that the final polyurea has a high thermal stability; the melting temperature is 269 degrees C and the decomposition temperature is above 300 degrees C. It is a brittle polymer with a tensile strength of 18.35 MPa at break length of 1.64%. The polyurea has a stronger solvent resistance due to the ordered hydrogen bond in structure. The average molecular weight should be enhanced in the post-polymerization as the appearance, hydrogen bond intensity, crystallinity, melting point and the thermal stability changed largely compared to the oligomer. The present work provides a new kind of polyurea, it is expected to have a wide application in the field of polymer materials. (C) 2017, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.
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