期刊
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
卷 7, 期 -, 页码 31-38出版社
ELSEVIER
DOI: 10.1016/j.cogsc.2017.07.001
关键词
-
资金
- National Key Research and Development Program [2016YFA0602900]
- National Natural Science Foundation of China [21472103, 21421001, 21421062, 21672119]
- Natural Science Foundation of Tianjin Municipality [16JCZDJC39900]
Nowadays, transformation of CO2 into value-added chemicals and fuels has attracted much attention. However, the inherent thermodynamic and kinetic limitation of CO2 represents the biggest obstacle associated with CO2 conversion. In this context, activation of CO2 would be prerequisite for its conversion. In this minireview, we would like to provide a concise overview of recent advances on CO2 activation by various organocatalysts including N-heterocyclic carbenes (NHCs)/Nheterocyclicolefins (NHOs), phosphorus ylides, polyoxometalates (POMs), ionic liquids (ILs), frustrated Lewis pairs (FLPs), superbases. In addition, carbon capture and utilization (CCU) strategy, the elegant combination of carbon capture and subsequent conversion, has also been summarized, which is designed to obviate the high energy input associated with carbon capture and storage/sequestration (CCS) process. In order to demonstrate the efficiency of CO2 activation, application of abovementioned CO2 activation in the synthesis of cyclic carbonates, carbon monoxide, quinazoline-2,4(1H, 3H)diones, methanol, oxazolidinones, formamides, ureas, alkyl 2alkynoates, alpha-hydroxy ketones, and formic acid are also included.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据